Bioplastics for eCommerce Packaging

FOR ENTERPRISE BRANDS

BIOPLASTICS FOR ECOMMERCE PACKAGING

by Saloni Doshi  • updated April 10 2025 • 8 minute read

Understanding what biopolymers are on the market, what questions to ask when sourcing materials, and making sense of the complex use cases of biopolymers.


At EcoEnclose, we're on a mission to develop truly sustainable packaging solutions for forward-thinking brands. Our vision rests on two key pillars: enhancing material circularity and pioneering the use of regenerative raw materials throughout our supply chain. We understand that achieving our regenerative materials vision requires introducing bio-based alternatives to fossil fuels.

However, "bioplastics" and "bio-derived inputs" are complex categories. Some bioplastics still rely on fossil fuels despite being biodegradable, while others come from renewable sources whose production methods may actually harm the environment. This complexity demands a thorough evaluation process and clear decision-making framework as we determine which bio innovations align with our sustainability goals and which don't.

Our Bio-Plastics Hub serves as a comprehensive resource for our team, EcoAllies, and curious individuals to understand the bio-alternative landscape and make informed choices about which paths to pursue.


Our Conclusions and Approach: When and How to Use Bioplastics in eCommerce Packaging

Questions to Ask About Bio Alternatives

The following is a list of questions we ask ourselves about bio-derived alternatives to plastic. These questions help create a larger framework for assessing materials. Our recent blog post, How EcoEnclose Evaluates Novel Materials provides more in-depth information on how we approach this research and assessment.

Inputs

  • What is the feedstock (source inputs) for this polymer?

    • Is it petroleum-based?

    • Is it grown in a degenerative way (i.e.massive monocrops like corn & sugarcane)?

    • Could it be created with regenerative inputs or novel waste streams?

    • Could it be created in a net-neutral or net positive way?

  • Is the feedstock degenerative by nature? In other words, is it net-positive, neutral, or negative in the following categories:

    • Land Impact

      • What is its land-use?

      • Does it require (now or in the future) clear-cutting of critical ecosystems for farming?

      • Does it threaten ancient or endangered forests?

      • Is it a monocrop?

      • Is it planted and grown in a regenerative growth cycle?

      • Does it need high levels of petroleum-based fertilizers and pesticides?

    • Carbon footprint

    • Reliance on petroleum-based products?

      • (i.e., polyvinyl acetate, ethylene glycol)

Functionality

  • What is it designed for functionally?

    • I.e., thin-film plastics, rigid plastics, agricultural applications, interaction with water, etc.

  • Does it behave in the same way as a traditional (petrol-based) plastic, or are there functional drawbacks?

    • I.e., shelf life, moisture barriers?

  • What is the formulation of the polymer?

    • New: A unique formulation that does not try to mimic a traditional petroleum-based plastic.

    • Drop-in: Identical on a molecular level to a fossil-fuel based plastic.

  • What would make this a better option than recycled plastics?

End-of-Life

  • What is its intended end of life/waste stream defined by the manufacturer or distributor?

  • How accessible to the average consumer is this intended end-of-life waste stream?

  • Does this waste stream have the capacity to accept and treat this material at mainstream/high volumes? Does the relevant waste industry want this material?

  • Does the technology to effectively treat this material exist widespread?

    • (i.e. filtration to capture microplastics or vinyl acetate in wastewater)

  • Does the material have the potential to create marine pollution (ocean plastics) or disintegrate into microplastics?

  • Is this material circular/closed loop by nature or linear by nature?

    • “Circular” meaning, could it be recirculated through recycling or existing systems to be made back into itself, thus closing the loop?

Our “Ideal” Bioplastic

Our vision of an ideal bioplastic is one whose production actively regenerates our planet—restoring soils, sequestering carbon, cleaning water, and supporting communities—while being infinitely recyclable into new packaging. We readily acknowledge that no current bioplastic fully achieves this ambitious standard.

At EcoEnclose, we emphasize progress over perfection. We embrace innovations that move our industry closer to this ultimate vision, even if they don't completely fulfill it yet. When evaluating bioplastics, we consider several critical factors outlined below.

We often find that recycled content outperforms many available bioplastic options from a sustainability perspective. However, we recognize that remaining in a cycle of recycling fossil fuel-derived plastics isn't a long-term solution. EcoEnclose must play an active role in accelerating the adoption of promising alternative materials.

We carefully assess each material using our framework, making deliberate decisions about which innovations to commercialize and which to postpone until their environmental profiles improve. Our approach balances immediate environmental impact with the long-term transformation our industry requires.

Inputs

  • Sourced from regenerative crops or bio feedstocks such as algae, seaweed, food waste, and agricultural residue.

  • Harvested without risk of endangering important ecosystems or placing pressure on these environments to support a higher and higher growth capacity.

  • Carbon neutral or negative. At the very least, it does not require more carbon input than recycled plastic would.

  • Note: Most materials do not check all of these boxes right away! We seek materials that have promise (even if they are not perfect today) and can scale efficiently.

Functionality

  • Meets the needs of eCommerce packaging or whatever packaging solution being replaced.

  • Compared to recycled plastic, it does not meaningfully sacrifice shelf-life, strength (tensile), and a range of applications and functions in a way that could lead to excess product damage.

  • Note: It is naive to expect a new material to have the exact functionality of the plastic it is replacing! The point here is not to ensure 1-1 functionality replacement, but to ensure that the bio alternative can perform successfully and not lead to excessive product damage.

End-of-Life

  • Able to be readily recycled in existing & accessible streams. Curbside recyclable is preferred.

  • Able to be closed-loop by design - the ability to be recycled back into itself.

  • Any bioplastic solution designed to dissolve in water should be non-toxic in aquatic environments.

  • Note: Recyclability—especially curbside recyclability—only becomes viable once a material reaches mainstream adoption and sufficient scale to justify investment by MRFs and remanufacturers. We don't allow our commitment to recyclability to prevent us from exploring promising innovations. When a bio-alternative demonstrates exceptional positive impact at the beginning of its lifecycle, we're likely to adopt it while simultaneously developing pathways toward eventual recyclability. During the early adoption phases of these materials, we recognize that composting often serves as the more practical and suitable end-of-life solution. In such cases, we accept compostability provided it meets third-party certification standards and doesn't introduce excessive contaminants into the resulting compost.


Types of Polymers

PVOH and PVA (Polyvinyl Alcohol)

dishwasher pod

Glue (polyvinyl acetate), water (through hydrolysis), and petroleum-based (PV).

Yes

New: a unique formulation that does not try to mimic a traditional petroleum-based plastic.
 
Used in dissolvable plastics including those used for food and medical, dishwasher and laundy detergents, and capsules meant for interaction with water.
 
Dissolved down the drain and water soluble.
 
Our Stance: This plastic works well when the item will dissolve anyway. It could be appropriate to incorporate in paper-based packaging in low volumes by weight to provide critical structural or strength properties. It should not be used as packaging on its own.
Research is still being done on this polymer's impact on the aquatic environment. A 2021 study recommends strict prudence when using this polymer widely for disposal in water.

Bio-PE and Bio-PET

laundry soap bottles
Sugarcane-sourced ethanol.
 

Yes

Drop-In: designed to mimic petroleum-based plastic counterparts; have the same end-of-life characteristics as the petroleum-based alternatives they mimic.
Used in LDPE, LLDPE, HDPE applications including thin film and rigid plastics.
Recycling.
 
Our Stance: These drop-in biopolymers are a great alternative to virgin polymers where they're required. Ideally, the source feedstock is regenerative and is used only when recycled plastics are not available or possible for the structure.

PLA and PBAT

compostable packaging
PLA: corn-based
PBAT: petroleum-based
 

Yes

New: a unique formulation that does not try to mimic a traditional petroleum-based plastic.

Initially used in food and beverage packaging and is now being used more broadly for other packaging applications.

Home or industrial compost.
 
Our Stance: These plastics should only be used as packaging for food or other material that should be composted. They should not be used for eCommerce or other clean packaging applications.

PBS

plastic cutlery
Polybutyl succinate which is currently petroleum-based. There is a potential to use monocrop agricultural waste as the feedstock.
 

Yes, however, it is possible to be circular if using existing waste streams, i.e. agricultural residues.

New: a unique formulation that does not try to mimic a traditional petroleum-based plastic.

Used for biomedical, agricultural applications and mulch films, food packaging, and tableware.

Biodegradation or industrial compost. Not backyard/home compostable certified and not recyclable.
 

Our Stance: Our preference is for materials that are readily recyclable.

PHA and PHB

compostable straws
Sugars, starches, and methane. This polymer is created through microbial digestion, camelina crop that is potentially regenerative, kelp and algae, and organic food waste.

Yes, however, it is possible to be circular if using existing waste streams, i.e. agricultural residues or municipal mixed compost.

New: a unique formulation that does not try to mimic a traditional petroleum-based plastic.

Applications where biodegration is a must such as fertilizer coatings, sutures, and agricultural applications.

Biodegradation in ambient environments. Not recyclable.
 

Our Stance: Our preference is for materials that are readily recyclable.

PEF

plastic packaging
Ethylene Glycol (petroleum-based, used to produce sealants and antifreeze), and FDCA (bio-based, generated when sugars are cooked or heated).

Yes.

Drop-In: designed to mimic petroleum-based plastic counterparts; have the same end-of-life characteristics as the petroleum-based alternatives they mimic.

Processed food additive (flavor or biomarker).

Recyclable and not biodegradable.
 
Our Stance: The inputs of this polymer could be promising if using an existing waste stream feedstock like municipal compost or food waste. It could also be an interesting application for PET purposes.

Cellophane (Cellulose)

plastic packaging
Cotton, wood, or hemp.

Yes.

New: a unique formulation that does not try to mimic a traditional petroleum-based plastic.

Clear films, food packaging, and packaging for products meant to biodegrade.

Biodegradation and industrial composting.
 
Our Stance: This polymer is OK when necessary assuming the feedstock inputs are produced in a net neutral or positive way (carbon, land use, and regenerative agricultural practices, existing cropland and not requiring deforestation or land conversion to produce cropland). It is not necessary or applicable for most eCommerce packaging applications.

Our Research

Explore our in-depth library of research and resources on bio-plastics, novel materials, and composting.


In-Depth Data

Landscape of Materials Overview

We highlight the market’s emerging and most common bioplastics. This chart provides an overview of each type of bioplastic, its typical applications and functions, feedstocks, and its designed disposal method.

Inputs and Feedstocks

We dive into the source inputs for these polymers. The chart showcases the source materials used to produce the polymer, its chemical makeup, and its creation process. This chart aims to provide you with a more holistic view of the impact of making each type of biopolymer. Recognize that the production of many biopolymer source feedstocks can be highly energy-intensive and polluting.

Рackaging Feedstocks:
A Comparative Landscape

EcoEnclose recognizes the need for renewable virgin inputs that contribute to environmental restoration. To uphold our vision of a circular packaging future, EcoEnclose has conducted extensive research on packaging inputs, including established options with solid impact data and more nascent options like organic waste and seaweed.

End of Life and Disposal

We detail what happens if a biopolymer is disposed of in various environments. Of course, it is easy to say that a specific biopolymer is “compostable” or “recyclable.” But to truly get at the “deep” questions that drive why brands are interested in bioplastics, it is critical to explore how materials will behave in all end-of-life situations.


Bioplastics Video Recap

Prefer to listen instead of read? Our Bioplastics and Dissolvable Plastics Crash Course video walks you through the main concepts of our white paper and research.